The Mass Spectrometry society of Japan - The 68th Annual Conference on Mass Spectrometry, Japan
Japanese

Abstract

Table of contents

Timetable

Plenary Lectures

Award Lecture

Oral Sessions (Day1, Day2, Day3)

Poster Presentations (Day1, Day2, Day3)

Panel Discussion

Luncheon Seminars (Day1, Day2, Day3)

Corporate Program

Oral Sessions

Day 1, June 22（Wed.）　17:45-18:00　Room D (413 and 414)

1D-O1-1745（1P-47）　　PDF

Mass Spectrometry of Volatile Compounds Emitted from Pyrolysis of Sulfur

(Yokohama City Univ.)
oTakeshi Osugi, Kanako Sekimoto

When sulfur is heated, sulfur changes from a yellow solid to a yellow liquid, a red viscous and a red black liquid. It has been known that the eight-membered ring structure is broken and polymerization occurs. But the structures of sulfur polymers are unknown. In this study, to estimate the sulfur structures, volatile products from heated sulfur were analyzed using an atmospheric pressure corona discharge ionization (APCDI) and a laser desorption ionization (LDI). In the process from a red viscous to a red black liquid, detected ions changed from S3- to HSO4- at APCDI. However, in the process from a yellow liquid to a red viscous, detected ions were S3- in APCDI and LDI.