The Mass Spectrometry society of Japan - The 71st Annual Conference on Mass Spectrometry, Japan
Japanese

Abstract

Table of contents

Timetable

Plenary Lecture

Symposium Sessions (Day1, Day2, Day3)

Basic Sessions (Day1, Day2, Day3)

Young Researchers' Sessions (Day1, Day2, Day3)

Poster Presentations (Day1, Day2, Day3)

Special Evening Sessions

Corporate Program

Basic Sessions

Day 2, May 16（Tue.）　09:51-10:09　Room B (Room 1202)

2B-O-0951　　PDF

Reaction Intermediates of Intramolecular Proton Transfer in Protonated Aminobenzoic Acid Observed by Ion Mobility–Mass Spectrometry

(Tohoku Univ.)
oKeijiro Ohshimo, Yuya Takasaki, Kengo Tsunoda, Ryosuke Ito, Manabu Kanno, Fuminori Misaizu

Intramolecular proton transfer reaction of protonated aminobenzoic acid in an ion trap induced by collision with ammonia was examined by cryogenic ion mobility-mass spectrometry. A complex ion of protonated aminobenzoic acid with ammonia was observed only when the ion trap was cooled with liquid nitrogen. This complex ion was concluded to be an intermediate of the vehicle mechanism in the proton transfer reaction from the structural assignment in the measurement of collision cross section.