The Mass Spectrometry society of Japan - The 71st Annual Conference on Mass Spectrometry, Japan

Abstract

Poster Presentations

Day 1, May 15(Mon.)  Room P (Foyer, Room 1004-1007)

Mass spectrometry of the plant-derived iron chelators

(1Suntory Foundation for Life Sciences, 2Tokushima Univ.)
oTakehiro Watanabe1, Yoshiko Murata1, Kosuke Namba2

Iron is an essential element for all living organisms, but iron in the alkaline soil is in the insoluble form, Fe(OH)3. Poaceae plants have a distinct chelation strategy to efficiently acquire insoluble soil iron using iron-chelating substances such as mugineic acids (MAs), called phytosiderophores. Nicotianamine, a precursor of MAs, transports absorbed iron in plant organisms. Therefore, iron chelators are a research subject with an important role for plants. However, quantitative analysis of phytosiderophore was very difficult due to its iron adsorption properties. Derivatization with 9-fluorenylmethyloxycarbonyl (Fmoc) reagent was effective for quantitative analysis.