ポスター発表
- 第3日 5月17日(金) P会場(多目的ホール)
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3P-29 PDF
FT-ICR質量スペクトルにおけるクーロン相互作用の影響に関するイオン分布解析
In a previous work, we have focused on the simulation for peak coalescence phenomena on FT-ICR mass spectra at a high magnetic field. The correlation between Coulomb-interaction-induced degradation of excited coherent ion cyclotron motion and FT-ICR mass spectral peak shape has been investigated in detail by many-particle simulation. In the present work, we have analyzed in more precise detail the ion cloud behavior during detection to elucidate the Coulomb-interaction-induced effects on FT-ICR mass spectra. The simulation results suggest that the relationship between the Coulomb-interaction-induced degradation and the spectral peak shape is quite complicated especially at a high magnetic field.