ポスター発表
第3日 6月12日(水) P会場(多目的ホール・大会議室101+102)P1会場(多目的ホール)・P2会場(会議室101+102)
- 3P-07
マトリックスの水素結合の強さから考えるMALDI-MSにおけるイオン化閾値
(広島大)
安慶名雛・ o山口愛歩・ 越智駿輔・ 高橋修・ 泉俊輔
In MALDI-MS, phenolic hydroxyl groups are known to be important as proton sources for the ionization of sample molecules. However, differences in ionization efficiency are observed even among matrices containing phenolic hydroxyl groups. In this study, we will discuss the nature of the hydrogen bonds between hydroxyl groups in the matrix and the relationship between the strength of the hydrogen bonds in the matrix and the ionization threshold.