演題概要

オーラルセッション

第1日 5月18日(水) 17:05~17:25 B会場(星雲1)

プロトン化アミノアルコールの高エネルギー電子移動解離で観測されるH2分子の連続脱離

(阪府大院理)
o早川滋雄羽田茉奈実中川淳貴藤原亮正麻田俊雄

High-energy electron transfer dissociation (HE-ETD) of singly protonated amino alcohols was investigated using charge inversion mass spectrometry with alkali metal targets in which dissociations were induced from the excited neutral intermediates. Consecutive dissociations of three H2 loss and that of H2 and NH3 loss from the charge reduced neutrals were observed. The relative intensities of these dissociation showed the clear dependence on the target alkali metal atoms.