Abstract

Table of contents

Plenary Lectures: Award Lectures
Oral Sessions Day1, Day2, Day3: Poster Presentations Day1, Day2, Day3
Workshop: Luncheon Seminars Day1, Day2, Day3
Timetable

Poster Presentations

Day 3, May 19（Fri.）　　Room P (Multi-purpose Hall)

3P-57　　PDF

Application of Derivatization for DART ionization

(JEOL)
^oKazuko Oka, Takaya Satoh, Masaaki Ubukata, Akihiko Kusai, Haruo Iwabuchi

Direct Analysis in Real Time(DART) has been coupled with the AccuTOF^TM LC-plus 4G atmospheric pressure ionization Time-of-Flight mass spectrometer to permit high-resolution, exact mass measurements of gases, liquids and solids. We studied the real-time derivatization such as methylation, acethylation and trimethylsilylation in DART ionization for sensitivity enhancement. In Me-derivatized compounds such as citrulline, L-cystathionine, it was also possible to confirm the existence of a compound capable of higher sensitivity detection than underivatized.