演題概要

オーラルセッション

第2日 6月18日(木) 9:10~9:30 D会場(202)

二次イオン質量分析(SIMS)の高感度化技術の開発:プロトン導電性イオン液体を用いたプロトン化の促進

(産総研)
o藤原幸雄齋藤直昭

Increasing secondary ion yields from organic and biological molecules is a major challenge in secondary ion mass spectrometry (SIMS). Enhancing protonation of organic analytes is essentially effective in increasing secondary ion yields. To enhance protonation, a proton-conducting ionic liquid was tested as both a liquid matrix and a primary ion beam. As a proton-conducting ionic liquid, Diethylmethylammonium trifluoromethanesulfonate, which is commonly abbreviated as [dema][TfO], was used. Obtained results of SIMS analysis showed that [dema][TfO] functioned well as both a liquid matrix and a primary ion beam.