The Mass Spectrometry society of Japan - The 68th Annual Conference on Mass Spectrometry, Japan

Abstract

Oral Sessions

Day 2, May 12(Tue.) 16:10-16:30 Room B (1202)

Development of a novel solvent-free applying method and application to mass imaging

(1AIST, 2Hamamatsu Photonics, 3GPI)
oSayaka Nakamura1, Thierry Fouquet1, Hiroaki Sato1, Takayuki Ohmura2, Masahiro Kotani2, Yasuhide Naito3

We have reported various analysis methods using porous structures of DIUTHAME. So far, only solution samples were able to be applied to a DIUTHAME tip. To extend the range of samples available, melting and thermal transfer procedures were introduced. Molten polyphenylene sulfide (an insoluble polymer in common solvents) gave a clear fragment peak corresponding to C6H4S2- ([monomer unit + S]-) in a negative mode. After heating dithranol, desorbed products were caught on a DIUTHAME tip and a characteristic peak was observed clearly. Moreover, this application method was applied to a mass imaging, a clear mass image of drawings was obtained.