The Mass Spectrometry society of Japan - The 68th Annual Conference on Mass Spectrometry, Japan
Japanese

Abstract

Table of contents

Timetable

Plenary Lectures

Oral Sessions (Day1, Day2, Day3)

Poster Presentations (Day1, Day2, Day3)

Workshops

Luncheon Seminars (Day1, Day2, Day3)

Poster Presentations

Day 1, May 11（Mon.）　　Poster (1008/09)

1P-26　　PDF

End Group Analysis of Poly(butylene terephthalate)s in Electrospray Ionization-Ion Mobility Spectrometry-Tandem Mass Spectrometry

(1NITech, 2Polyplastics)
oYuki Morimoto1, Shinya Kitagawa1, Hajime Ohtani1, Kuniaki Kawaguchi2, Hiroaki Akutsu2

In this study, we demonstrated the end group of analysis of poly(butylene terephthalate)s (PBTs) in electrospray ionization-ion mobility spectrometry-tandem MS (ESI-IMS-MS/MS) with collision-induced charge stripping (CICS). Hydrolyzed PBTs weighing approximately 9 kDa was separated into 8 groups on 2D distribution (m/z-drift time) do to the difference in z values in ESI-IMS-MS, and the end groups of PBTs in each group were successfully identified. For the identification of cyclic oligomers of z =1, it was revealed that the analysis based on the drift time in IMS was effective. PBTs weighing approximately 40 kDa were analyzed in ESI-MS-IMS-CICS-MS, and the identification of the end groups of PBTs weighing approximately 20 kDa and 30 kDa were successfully achieved.