日本質量分析学会 第71回質量分析総合討論会

演題概要

若手研究者セッション

第2日 5月16日(火) 09:15~09:30 C会場(会議室1009)

大気圧コロナ放電イオン化質量分析によるリンゴ発散香気成分のプロファイリング

(横市大院生命ナノ)
o錦戸悠斗関本奏子

Apples are the world's largest fruit in both production and consumption, and their fresh aroma is one of the reasons for their popularity. Apple aroma compounds have been studied previously, but all methods have problems such as long measurement time or processing. In this study, volatile compounds emitted from intact apples were analyzed using an atmospheric pressure corona discharge ionization (APCDI) method combined with collision-induced dissociation mass spectrometry, which require no pretreatment and short measurement time. Apples measured were Fuji, Gala, Akane, Sansa, Jonagold, Golden Delicious, Jonathan, Tsugaru, and Orin. Detected major ion peaks were protonated molecules of saturated esters [CxH2xO2+H]+ (x=2-12) for all the apples. The distribution of ester isomers for each CxH2xO2 depends upon apple cultivars. For example, the relative intensities at R1=C4H9 were large in Fuji, but small in Sansa. This is an indication of specificity among varieties.