日本質量分析学会 第71回質量分析総合討論会

演題概要

ポスター発表

第1日 5月15日(月)  P会場(ホワイエ,会議室1004-1007)

植物性鉄キレート化合物の質量分析

(1サントリー生科財団2徳島大院医歯薬)
o渡辺健宏1村田佳子1難波康佑2

Iron is an essential element for all living organisms, but iron in the alkaline soil is in the insoluble form, Fe(OH)3. Poaceae plants have a distinct chelation strategy to efficiently acquire insoluble soil iron using iron-chelating substances such as mugineic acids (MAs), called phytosiderophores. Nicotianamine, a precursor of MAs, transports absorbed iron in plant organisms. Therefore, iron chelators are a research subject with an important role for plants. However, quantitative analysis of phytosiderophore was very difficult due to its iron adsorption properties. Derivatization with 9-fluorenylmethyloxycarbonyl (Fmoc) reagent was effective for quantitative analysis.