日本質量分析学会 第69回質量分析総合討論会会

演題概要

オーラルセッション

第2日 5月20日(木) 11:00~11:20 E会場(Zoom)

中性ラジカル-イオン反応を用いた新規LCMS-Q-TOF型質量分析計の開発

(島津)
o高橋秀典古田匡智乾公隆三井一高岩本慎一田中耕一

Conventional collision-induced dissociation (CID)-MS/MS utilizes rare gas or nitrogen molecules as collision gas. Our research group has developed a new radical-induced dissociation (RID)-MS/MS using charge-neutral and highly reactive radical gas instead of collision gas. In this study, we developed a novel LCMS-Q-TOF mass spectrometer employing RID-MS/MS of oxygen attachment dissociation (OAD). OAD-MS/MS, which integrates injection of OH• and atomic O, has made it possible to accomplish the detailed structural analysis of biomolecules.