日本質量分析学会 第68回質量分析総合討論会会

演題概要

ポスター発表

第1日 5月11日(月)  P会場(1008/09)

CO3・-による水素引き抜き反応の試料特性

(横市大院生命ナノ)
o川島萌高山光男関本奏子

The oxidation reaction includes oxygen attachment reaction and hydrogen abstraction reaction. The latter is known to cause aging, cancer and Alzheimer's disease in vivo. In this study, we examined how hydrogen is abstracted from analytes by CO3・-, using analytes with various different physicochemical properties and atmospheric pressure corona discharge ionization mass spectrometry (APCDI-MS). The results suggested that degree of hydrogen abstraction depends on the properties of the functional groups of analytes and the bond energy between each atom.